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022 | _a09743626 | ||
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_aMSU _bEnglish _cMSU _erda |
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050 | 0 | 0 | _aQD31 JOU |
100 | 1 |
_aSheikhshoaie, Iran _eauthor |
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245 | 1 | 0 |
_aSynthesis, characterization, X-ray crystal structure, electrochemical evaluation and anti-cancer studies of a mixed ligand Cu(II) complex of (E)-N′-((2-hydroxynaphthalen-1-yl)methylene)acetohydrazide / _ccreated by Iran Sheikhshoaie, S. Yousef Ebrahimipour, Mahdieh Sheikhshoaie, Maryam Mohamadi, Mehdi Abbasnejad, Hadi Amiri Rudbari and Giuseppe Bruno |
264 | 1 |
_aBangalore : _bSpringer, _c2015. |
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336 |
_2rdacontent _atext _btxt |
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337 |
_2rdamedia _aunmediated _bn |
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338 |
_2rdacarrier _avolume _bnc |
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440 |
_aJournal of chemical sciences _vVolume 127, number 12, |
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520 | 3 | _aA ternary mixed ligand Cu(II) complex, [Cu(L)(Phen)], was prepared from the reaction of (E)-N′-((2-hydroxynaphthalen-1-yl)methylene)acetohydrazide [HL], Cu(NO3)2.3H2O and 1,10-Phenanthroline in 1:1:1 molar ratio. This complex was fully characterized using spectroscopic and physicochemical methods. The structure of the complex was determined by single crystal X-ray diffraction. The Cu(II) center is coordinated by two oxygen and one nitrogen donors of L2− and nitrogen atoms of the heterocyclic group. Electrochemical studies of the Cu(II) complex showed shifts in the ligand peaks as well as the appearance of new peaks after complexation. The electrochemical behavior of the Cu(II) complex was also studied using cyclic voltammetry. According to biochemical investigation (MCF-7 cells viability), anticancer activity of [Cu(L)(Phen)] was higher than those of Cu(NO3)2.3H2O, HL and 1,10-Phenanthroline. | |
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_aSchiff base _vCu(II) complex _xAnticancer activity |
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700 | 1 |
_aEbrahimipour, S. Yousef _eco author |
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700 | 1 |
_aSheikhshoaie, Mahdieh _eco author |
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700 | 1 |
_aMohamadi, Maryam _eco author |
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700 | 1 |
_aAbbasnejad, Mehdi _eco author |
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700 | 1 |
_aRudbari, Hadi Amiri _eco author |
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700 | 1 |
_aBruno, Giuseppe _eco author |
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856 | _uhttps://doi.org/10.1007/s12039-015-0978-8 | ||
942 |
_2lcc _cJA |
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_c169423 _d169423 |