000 | 01679nam a22002657a 4500 | ||
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003 | ZW-GwMSU | ||
005 | 20250318100107.0 | ||
008 | 250318b |||||||| |||| 00| 0 eng d | ||
022 | _a09743626 | ||
040 |
_aMSU _bEnglish _cMSU _erda |
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050 | 0 | 0 | _aQD31 JOU |
100 | 1 |
_aSingh, Ashish _eauthor |
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245 | 1 | 0 |
_aIntroduction of an electron push-pull system yields a planar Red Kaede fluorescence protein chromophore analogue stabilized by a C = O…π interaction / _ccreated by Ashish Singh, Basanta Kumar Rajbongshi and Gurunath Ramanathan |
264 | 1 |
_aBangalore : _bSpringer, _c2015. |
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336 |
_2rdacontent _atext _btxt |
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337 |
_2rdamedia _aunmediated _bn |
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338 |
_2rdacarrier _avolume _bnc |
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440 |
_aJournal of chemical sciences _vVolume 127, number 5, |
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520 | 3 | _aCrystal structures of four red kaede fluorescence protein chromophore analogues are reported here. Molecules I-III adopt a non-planar geometry stabilized by π…π stacking and hydrogen bonding. Introduction of an electron push-pull system induces molecule IV to be planar and a C = O…π supramolecular interaction is observed as well. Strong electron withdrawing and donating groups also ensure formation of a higher order two and three dimensional supramolecular architecture through hydrogen bonds in molecules I and IV. All the analogues exhibit good photoluminescence properties and emit in the red region with excellent quantum yields. | |
650 |
_aImidazolin-5-one _vRFP chromophore _xC = O…π stacking |
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700 | 1 |
_aRajbongshi, Basanta Kumar _eco author |
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700 | 1 |
_aRamanathan, Gurunath _eco author |
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856 | _uhttps://doi.org/10.1007/s12039-015-0855-5 | ||
942 |
_2lcc _cJA |
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999 |
_c169341 _d169341 |