000			02111nam a22002777a 4500
003			ZW-GwMSU
005			20250318083944.0
008			250318b |||||||| |||| 00| 0 eng d
022			_a09743626
040			_aMSU _bEnglish _cMSU _erda
050	0	0	_aQD31 JOU
100	1		_aDutta, Alokdut _eauthor
245	1	0	_aEffect of optimized structure and electronic properties of some benzimidazole derivatives on corrosion inhibition of mild steel in hydrochloric acid medium : _belectrochemical and theoretical studies / _ccreated by Alokdut Dutta, Sujit Sankar Panja, M. M. Nandi and Dipankar Sukul
264	1		_aBangalore : _bSpringer, _c2015.
336			_2rdacontent _atext _btxt
337			_2rdamedia _aunmediated _bn
338			_2rdacarrier _avolume _bnc
440			_aJournal of chemical sciences _vVolume 127, number 5,
520	3		_aThe corrosion inhibitive action of a few benzimidazole derivatives namely 2-(benzamido) ethylbenzimidazole (BAEBI), 2-(β-benzenesulphonamido) ethylbenzimidazole (BSAEBI), 2-(benzamido) methylbenzimidazole (BAMBI) and 2-(β-benzenesulphonamido) methylbenzimidazole (BSAMBI), towards mild steel in hydrochloric acid has been studied using potentiodynamic polarization and electrochemical impedance spectroscopic (EIS) methods. The results show that these compounds get adsorbed on the mild steel surface following Temkin adsorption isotherm, and act as mixed-type inhibitors. The inhibition efficiencies are found to follow the order, BAEBI > BSAEBI > BAMBI > BSAMBI. This observation is explained in terms of chain length, relative effects of amido and sulphonamido groups, possible structural factors, spatial orientations, energy gap between the frontier molecular orbitals, different intrinsic molecular parameters, like, global hardness and softness, and number of electrons transferred.
650			_aAdsorption _vCorrosion inhibition _xElectrochemical techniques
700	1		_aPanja, Sujit Sankar _eco author
700	1		_aNandi, M. M. _eco author
700	1		_aSukul, Dipankar _eco author
856			_uhttps://doi.org/10.1007/s12039-015-0850-x
942			_2lcc _cJA
999			_c169336 _d169336