| 000 | 02305nam a22003017a 4500 | ||
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| 003 | ZW-GwMSU | ||
| 005 | 20250318082005.0 | ||
| 008 | 250318b |||||||| |||| 00| 0 eng d | ||
| 022 | _a09743626 | ||
| 040 |
_aMSU _bEnglish _cMSU _erda |
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| 050 | 0 | 0 | _aQD31 JOU |
| 100 | 1 |
_aSrinivas, M. _eco author |
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| 245 | 1 | 0 |
_aUnderstanding the surface and structural characteristics of tungsten oxide supported on tin oxide catalysts for the conversion of glycerol / _ccreated by M. Srinivas, G. Raveendra, G. Parameswaram, P. S. Sai Prasad, S. Loridant and N. Lingaiah |
| 264 | 1 |
_aBangalore : _bSpringer, _c2015. |
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| 336 |
_2rdacontent _atext _btxt |
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| 337 |
_2rdamedia _aunmediated _bn |
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| 338 |
_2rdacarrier _avolume _bnc |
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| 440 |
_aJournal of chemical sciences _vVolume 127, number 5, |
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| 520 | 3 | _aCatalysts with varying WO3 content on SnO2 were prepared and characterized by X-ray diffraction, in situ Raman spectroscopy, X-ray photoelectron spectroscopy and temperature programmed desorption of NH3. In situ Raman analysis reveals the presence isolated monomers and polymeric species of WO3. These catalysts were evaluated for the conversion of glycerol into value added chemicals. Etherification of glycerol with tertiary butanol and preparation of glycerol carbonate from glycerol and urea are studied over these catalysts. The catalytic activity results suggest that the glycerol conversion and selectivity depends on the morphology of WO3 which in turn is related to its content in the catalyst. The catalysts with 5 wt.% of WO3 on SnO2 resulted in high dispersion with larger number of strong acidic sites. The selectivity in the glycerol etherification is related to the nature of the catalyst and reaction time. These catalysts also exhibited high activity for synthesis of glycerol carbonate. The effect of various reaction parameters was studied to optimize the reaction conditions. The catalysts also exhibited consistent activity upon reuse. | |
| 650 |
_aTungsten oxide _vTin oxide _xEtherification |
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| 700 | 1 |
_aRaveendra, G. _eco author |
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| 700 | 1 |
_aParameswaram, G. _eco author |
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| 700 | 1 |
_aPrasad, P. S. Sai _eco author |
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| 700 | 1 |
_aLoridant, S. _eco author |
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| 700 | 1 |
_aLingaiah, N. _eco author |
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| 856 | _uhttps://doi.org/10.1007/s12039-015-0848-4 | ||
| 942 |
_2lcc _cJA |
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| 999 |
_c169332 _d169332 |
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