000 01643nam a22002657a 4500
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022 _a09743626
040 _aMSU
_bEnglish
_cMSU
_erda
050 0 0 _aQD31 JOU
100 1 _aBamoniri, A.
_eauthor
245 1 0 _aNano-TiCl4/SiO2 :
_ban efficient heterogeneous solid acid catalyst for the one pot cascade five-component synthesis of densely functionalized tetrahydropyridines /
_ccreated by A. Bamoniri, B. Mirjalili and Reza Tarazian
264 1 _aBangalore :
_bSpringer,
_c2015.
336 _2rdacontent
_atext
_btxt
337 _2rdamedia
_aunmediated
_bn
338 _2rdacarrier
_avolume
_bnc
440 _aJournal of chemical sciences
_vVolume 127, number 5,
520 3 _aNano-TiCl4/SiO2 was found to be an inexpensive and efficient heterogeneous solid acid catalyst for the synthesis of one-pot cascade synthesis of highly functionalized asymmetric tetrahydropyridines from the five-component condensation reaction of the para-substituted anilines and aromatic aldehydes with ethyl acetoacetate under thermal conditions. Novel methodology, environmentally benign conditions, clean protocol, easy work-up and high yields are the important advantages of this protocol. The products were characterized using physical and spectroscopic data such as FT-IR, 1H-NMR and in some cases 13C-NMR and CHN analysis.
650 _aTetrahydropyridines
_vNano-TiCl4/SiO2
_xHeterogeneous catalyst
700 1 _aMirjalili, B.
_eco author
700 1 _aTarazian, Reza
_eco author
856 _uhttps://doi.org/10.1007/s12039-015-0845-7
942 _2lcc
_cJA
999 _c169327
_d169327