000			02064nam a22002777a 4500
003			ZW-GwMSU
005			20250318073316.0
008			250318b |||||||| |||| 00| 0 eng d
022			_a09743626
040			_aMSU _bEnglish _cMSU _erda
050	0	0	_aQD31 JOU
100	1		_aPalanisami, Nallasamy _eauthor
245	1	2	_aA mixed Ni(II) ionic complex containing V-shaped water trimer : _bsynthesis, spectral, structural and thermal properties of {[Ni(2,2′-bpy)3][Ni(2-cpida)(2,2′ -bpy)]} (ClO4).3H2O / _ccreated by Nallasamy Palanisami, Kabali Senthilkumar, Mohan Gopalakrishnan and Il-Shik Moon
264	1		_aBangalore : _bSpringer, _c2015.
336			_2rdacontent _atext _btxt
337			_2rdamedia _aunmediated _bn
338			_2rdacarrier _avolume _bnc
440			_aJournal of chemical sciences _vVolume 127, number 5,
520	3		_aA mixed Ni(II) ionic complex of {[Ni(2,2′-bpy)3][Ni(2-cpida)(2,2′-bpy)]}(ClO4).3H2O (1) (2-H3cpida = N-(2-carboxyphenyl)iminodiacetic acid, 2,2′-bpy = 2,2′-bipyridyl) has been synthesized and characterized by infrared, ultraviolet and fluorescence spectroscopy, elemental and thermogravimetric analysis. The molecular structure of compound 1, as determined by single-crystal X-ray diffraction studies, showed all the three carboxylate groups are in monodendate mode. Compound 1 consists of a discrete mononuclear [Ni(2,2′-bpy)3]2+ cation, a [Ni(2-cpida)(2,2′-bpy)]− anion, a ClO 4 − anion and three lattice water molecules. The H-bonding interaction between three lattice water molecule forms a V-shaped trimer (H2O)3 which gives rise to a 1-D polymeric structure in the solid state. Graphical Abstract A mixed ionic complex of Ni(II) contains V-shaped water trimer (H2O)3 through inter molecular hydrogen bonding interactions.
650			_aIonic complex _vHydrogen bonding _xWater trimer
700	1		_aSenthilkumar, Kabali _eco author
700	1		_aGopalakrishnan, Mohan _eco author
700	1		_aMoon, Il-Shik _eco author
856			_uhttps://doi.org/10.1007/s12039-015-0843-9
942			_2lcc _cJA
999			_c169325 _d169325