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022 _a09743626
040 _aMSU
_bEnglish
_cMSU
_erda
050 0 0 _aQD31 JOU
100 1 _aRamesh, T.N.
_eauthor
245 1 0 _aPara-amino benzoic acid–mediated synthesis of vaterite phase of calcium carbonate /
_ccreated by T.N. Ramesh, S.A. Inchara and K. Pallavi
264 1 _aBangalore :
_bSpringer,
_c2015.
336 _2rdacontent
_atext
_btxt
337 _2rdamedia
_aunmediated
_bn
338 _2rdacarrier
_avolume
_bnc
440 _aJournal of chemical sciences
_vVolume 127, number 5,
520 3 _aCalcium carbonate polymorphs were precipitated at room temperature and 80∘C by varying the precipitation pH, carbonate source, effect of solvent in presence and absence of structure directing agent such as para-aminobenzoic acid. Calcite phase of calcium carbonate was obtained when sodium hydrogen carbonate and/or sodium carbonate (used as precipitating agents) were added to calcium chloride solution at different pHs in water and/or methanol as solvent in separate experiments. Vaterite phase of calcium carbonate (CaCO3) has been synthesized by mixing calcium chloride and sodium carbonate in presence of para-aminobenzoic acid when water–methanol binary mixture was used as solvent. Vaterite phase of calcium carbonate crystallizes in P63/mmc, while that of calcite phase in R-3mc, respectively. Calcite phase of calcium carbonate exhibits rhombohedral morphology, while vaterite phase has spherical morphology.
650 _aCalcium carbonate
_vChemical synthesis
_xVaterite
700 1 _aInchara, S.A.
_eco author
700 1 _aPallavi, K.
_eco author
856 _uhttps://doi.org/10.1007/s12039-015-0849-3
942 _2lcc
_cJA
999 _c169318
_d169318