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022 | _a09743626 | ||
040 |
_aMSU _bEnglish _cMSU _erda |
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050 | 0 | 0 | _aQD31 JOU |
100 | 1 |
_aRamesh, T.N. _eauthor |
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245 | 1 | 0 |
_aPara-amino benzoic acid–mediated synthesis of vaterite phase of calcium carbonate / _ccreated by T.N. Ramesh, S.A. Inchara and K. Pallavi |
264 | 1 |
_aBangalore : _bSpringer, _c2015. |
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336 |
_2rdacontent _atext _btxt |
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337 |
_2rdamedia _aunmediated _bn |
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338 |
_2rdacarrier _avolume _bnc |
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440 |
_aJournal of chemical sciences _vVolume 127, number 5, |
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520 | 3 | _aCalcium carbonate polymorphs were precipitated at room temperature and 80∘C by varying the precipitation pH, carbonate source, effect of solvent in presence and absence of structure directing agent such as para-aminobenzoic acid. Calcite phase of calcium carbonate was obtained when sodium hydrogen carbonate and/or sodium carbonate (used as precipitating agents) were added to calcium chloride solution at different pHs in water and/or methanol as solvent in separate experiments. Vaterite phase of calcium carbonate (CaCO3) has been synthesized by mixing calcium chloride and sodium carbonate in presence of para-aminobenzoic acid when water–methanol binary mixture was used as solvent. Vaterite phase of calcium carbonate crystallizes in P63/mmc, while that of calcite phase in R-3mc, respectively. Calcite phase of calcium carbonate exhibits rhombohedral morphology, while vaterite phase has spherical morphology. | |
650 |
_aCalcium carbonate _vChemical synthesis _xVaterite |
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700 | 1 |
_aInchara, S.A. _eco author |
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700 | 1 |
_aPallavi, K. _eco author |
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856 | _uhttps://doi.org/10.1007/s12039-015-0849-3 | ||
942 |
_2lcc _cJA |
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_c169318 _d169318 |