000			01977nam a22002537a 4500
003			ZW-GwMSU
005			20250317093533.0
008			250317b |||||||| |||| 00| 0 eng d
022			_a09743626
040			_aMSU _bEnglish _cMSU _erda
050	0	0	_aQD31 JOU
100	1		_aIslam, Nashreen S. _eauthor
245	1	0	_aMacromolecular peroxo complexes of Vanadium(V) and Molybdenum(VI): Catalytic activities and biochemical relevance / _ccreated by Nashreen S. Islam and Jeena Jyoti Boruah
264	1		_aBangalore : _bSpringer, _c2015.
336			_2rdacontent _atext _btxt
337			_2rdamedia _aunmediated _bn
338			_2rdacarrier _avolume _bnc
440			_aJournal of chemical sciences _vVolume 127, number 5,
520	3		_aOur recent achievements concerning the synthesis and characterization of water soluble peroxo complexes of V(V) and Mo(VI) in macroligand environment, as well as some key features of biological relevance of these compounds, such as their hydrolytic stability, activity with phosphohydrolase enzyme vis-à-vis free peroxovanadium (pV) or peroxomolybdenum (pMo) complexes, and their activity in biomimetic oxidative bromination are presented here. Immobilization of pMo species on insoluble polymer matrices viz., amino acid functionalized Merrifield resins and poly(acrylonitrile) on the other hand, afforded a set of heterogeneous catalysts highly effective in facile organic transformations such as selective oxidation of organic sulfides and oxidative bromination of aromatic substrates by H2O2, at ambient temperature. The methodologies are straightforward, high-yielding, halogen-free and the catalysts afford easy regeneration. Our findings illustrate the various features which make the procedures sustainable and synthetically useful.
650			_aMacromolecular metal complexes _vPeroxovanadates _xPeroxomolybdates
700	1		_aBoruah, Jeena Jyoti _eco author
856			_uhttps://doi.org/10.1007/s12039-015-0833-y
942			_2lcc _cJA
999			_c169306 _d169306