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| 003 | ZW-GwMSU | ||
| 005 | 20250317085015.0 | ||
| 008 | 250317b |||||||| |||| 00| 0 eng d | ||
| 022 | _a09743626 | ||
| 040 |
_aMSU _bEnglish _cMSU _erda |
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| 050 | 0 | 0 | _aQD31 JOU |
| 100 | 1 |
_aPandey, Bhawana _eauthor |
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| 245 | 1 | 0 |
_aStructures, bonding and reactivity of iron and manganese high-valent metal-oxo complexes : _ba computational investigation / _ccreated by Bhawana Pandey, Azaj Ansari, Nidhi Vyas and Gopalan Rajaraman |
| 264 | 1 |
_aBangalore : _bSpringer, _c2015. |
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| 336 |
_2rdacontent _atext _btxt |
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| 337 |
_2rdamedia _aunmediated _bn |
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| 338 |
_2rdacarrier _avolume _bnc |
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| 440 |
_aJournal of chemical sciences _vVolume 127, number 2, |
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| 520 | 3 | _aIron and manganese ions with terminal oxo and hydroxo ligands are discovered as key intermediates in several synthetic and biochemical catalytic cycles. Since many of these species possess vigorous catalytic abilities, they are extremely transient in nature and experiments which probe the structure and bonding on such elusive species are still rare. We present here comprehensive computational studies on eight iron and manganese oxo and hydroxo (FeIII/IV/V-O, FeIII-OH and MnIII/IV/V-O, MnIII-OH) species using dispersion corrected (B3LYP-D2) density functional method. By computing all the possible spin states for these eight species, we set out to determine the ground state S value of these species; and later on employing MO analysis, we have analysed the bonding aspects which contribute to the high reactivity of these species. Direct structural comparison to iron and manganese-oxo species are made and the observed similarity and differences among them are attributed to the intricate metal–oxygen bonding. By thoroughly probing the bonding in all these species, their reactivity towards common chemical reactions such as C–H activation and oxygen atom transfer are discussed. | |
| 650 |
_aElectronic structures and bonding _vDFT calculations _xHigh-valent iron and manganese |
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| 700 | 1 |
_aAnsari, Azaj _eco author |
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| 700 | 1 |
_aVyas, Nidhi _eco author |
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| 700 | 1 |
_aRajaraman, Gopalan _eco author |
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| 856 | _uhttps://doi.org/10.1007/s12039-015-0770-9 | ||
| 942 |
_2lcc _cJA |
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| 999 |
_c169304 _d169304 |
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