000			01932nam a22002537a 4500
003			ZW-GwMSU
005			20250317063838.0
008			250317b |||||||| |||| 00| 0 eng d
022			_a09743626
040			_aMSU _bEnglish _cMSU _erda
050	0	0	_aQD31 JOU
100	1		_aDurgaprasad, Gummadi _eauthor
245	1	0	_aModeling the active site of [FeFe]-hydrogenase : _bElectro-catalytic hydrogen evolution from acetic acid catalysed by [Fe 2 (μ-L)(CO) 6 ] and [Fe 2 (μ-L)(CO) 5 (PPh 3 )] (L=pyrazine-2,3-dithiolate, quinoxaline-2,3-dithiolate and pyrido[2,3-b]pyrazine-2,3-dithiolate) / _ccreated by
264	1		_aBangalore : _bSpringer, _c2015.
336			_2rdacontent _atext _btxt
337			_2rdamedia _aunmediated _bn
338			_2rdacarrier _avolume _bnc
440			_aJournal of chemical sciences _vVolume 127, number 2,
520	3		_aCompounds [Fe2{ μ-pydt}(CO)6] (pydt = pyrazine-2,3-dithiolate) (1), [Fe2{ μ-qdt}(CO)6] (qdt = quinoxaline-2,3-dithiolate) (2), [Fe2{ μ-ppdt}(CO)6] (ppdt = pyrido[2,3-b]pyrazine-2,3-dithiolate) (3), [Fe2 { μ-pydt}(CO)5PPh3] (4), [Fe2{ μ-qdt}(CO)5PPh3] (5) and [Fe2{ μ-ppdt}(CO)5PPh3] (6) have been synthesized in order to model the active sites of ‘[FeFe]-hydrogenase’. Compounds 1–6 have been characterized by routine spectral studies and unambiguously by single crystal X-ray crystallography. Supramolecular chemistry of compounds 1–6 have been described in terms of intermolecular interactions, observed in their respective crystal structures. Electro-catalytic hydrogen evaluation studies (from acetic acid) have been performed using compounds 1–6 as electro-catalysts. The mechanistic aspects of relevant electro–catalytic proton reductions have been discussed in detail.
650			_aModeling the active site _v[FeFe]-hydrogenase _xSpectroscopy
700	1		_aDas, Samar K. _eco author
856			_uhttps://doi.org/10.1007/s12039-015-0774-5
942			_2lcc _cJA
999			_c169298 _d169298