| 000 | 01895nam a22002657a 4500 | ||
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| 003 | ZW-GwMSU | ||
| 005 | 20250312064845.0 | ||
| 008 | 250312b |||||||| |||| 00| 0 eng d | ||
| 022 | _a09743626 | ||
| 040 |
_aMSU _bEnglish _cMSU _erda |
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| 050 | 0 | 0 | _aQD31 JOU |
| 100 | 1 |
_aNaranthatta, Mili C. _eauthor |
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| 245 | 1 | 0 |
_aRole of peripheral phenanthroline groups in the self-assembly of self-assembled molecular triangles / _ccreated by Mili C. Naranthatta, Venkatachalam Ramkumar and Dillip Kumar Chand |
| 264 | 1 |
_aBangalore : _bSpringer, _c2015. |
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| 336 |
_2rdacontent _atext _btxt |
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| 337 |
_2rdamedia _aunmediated _bn |
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| 338 |
_2rdacarrier _avolume _bnc |
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| 440 |
_aJournal of chemical sciences _vVolume 127, number 2, |
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| 520 | 3 | _aSelf-assembled molecular triangles [Pd3(phen)3(imidazolate)3](NO3)3, 1a and [Pd3(phen)3 (imidazolate)3](PF6)3, 1b are prepared by the combination of imidazole with Pd(phen)(NO3)2 and Pd(phen) (PF6)2, respectively. Imidazole was deprotonated during the complexation reactions and the imidazolate so formed acted as a bis-monodentate bridging ligand to form the bowl-shaped trinuclear architectures of 1a/b. Relative orientation of the imidazolate moieties can be best described as syn,anti,antias observed in the crystal structure of 1b. However, in solution state, slow conformational changes are assumed on the basis of 1HNMR spectral data. The molecular triangles are crafted with three peripheral phen units capable of π−π stacking interactions. Well-fashioned intermolecular π−π interactions are observed in the solid-state, wherein further self-assembly of already self-assembled triangle is observed. | |
| 650 |
_aPalladium(II) _v1,10-phenanthroline _xImidazole |
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| 700 | 1 |
_aRamkumar, Venkatachalam _eco author |
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| 700 | 1 |
_aChand, Dillip Kumar _eco author |
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| 856 | _uhttps://doi.org/10.1007/s12039-015-0776-3 | ||
| 942 |
_2lcc _cJA |
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| 999 |
_c169257 _d169257 |
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