000			02112nam a22002657a 4500
003			ZW-GwMSU
005			20250311141806.0
008			250311b |||||||| |||| 00| 0 eng d
022			_a09743626
040			_aMSU _bEnglish _cMSU _erda
050	0	0	_aQD31 JOU
100	1		_aGoswami, Soumyabrata _eauthor
245	1	0	_aExploration of the structural features and magnetic behaviour in a novel 3-dimensional interpenetrating Co(II)-based framework / _ccreated by Soumyabrata Goswami, A. Mondal, Sanjit Konar
264	1		_aBangalore : _bSpringer, _c2015.
336			_2rdacontent _atext _btxt
337			_2rdamedia _aunmediated _bn
338			_2rdacarrier _avolume _bnc
440			_aJournal of chemical sciences _vVolume 127, number 2,
520	3		_aA new Co(II)-based three-dimensional (3D) framework having the molecular formula [Co(C4O4)(4-bpmh))H2O)2]n·2nH2O·2nMeOH·(1) (4-bpmh=N, N-bis-pyridin-4-ylmethylene-hydrazine) has been syn-thesized using a mixed ligand system and characterized by elemental analysis, IR spectroscopy, thermogravi-metric analysis, single crystal X-ray diffraction and variable temperature magnetic study. The framework isconstructed by the bridging squarate (C4O2−4)and N, N-bis-pyridin-4-ylmethylene-hydrazine (4-bpmh) ligandsand interpenetration of the 2D grid-like frameworks at definite angles gives rise to 2D→3D inclined polycate-nation with sql/Shubnikov tetragonal plane net topology. Extensive non-covalent interactions (H-bonding aswell asπ···πinteractions) are also observed which stabilises the 3D arrangement. Additionally, complex1contains 1D channels of large dimensions (10.91×11.78 Å2)that runs along theb-axis. Variable temperatureDC magnetic susceptibility study reveals dominant spin–orbit coupling effect typical of the4T1gground stateof octahedral high-spin Co(II) ion at a higher temperature range.
650			_aMixed ligand system _vCo(II)-based 3D framework _xInterpenetrated structure
700	1		_aMondal, A. _eco author
700	1		_aKonar, Sanjit _eco author
856			_uhttps://doi.org/10.1007/s12039-015-0771-8
942			_2lcc _cJA
999			_c169253 _d169253