000			01790nam a22002537a 4500
003			ZW-GwMSU
005			20250311123646.0
008			250311b |||||||| |||| 00| 0 eng d
022			_a09743626
040			_aMSU _bEnglish _cMSU _erda
050	0	0	_aQD31 JOU
100	1		_aMukherjee, Sanjoy _eauthor
245	1	0	_aFrustrated lewis pairs : _bdesign and reactivity / _ccreated by Sanjoy Mukherjee and Pakkirisamy Thilagar
264	1		_aBangalore : _bSprinter, _c2015.
336			_2rdacontent _atext _btxt
337			_2rdamedia _aunmediated _bn
338			_2rdacarrier _avolume _bnc
440			_aJournal of chemical sciences _vVolume 127, number 2,
520	3		_aThe interaction of a Lewis acid with a Lewis base results in the formation of a Lewis acid–base adduct. Understanding Lewis acids and bases is central to conceptualizing chemical interactions and constitutes a major portion of metal–ligand chemistry. Sterically encumbered/constrained Lewis pairs cannot form acid–base adducts, but such ‘Frustrated Lewis Pairs’ (FLPs), with their unquenched electronic demands can be elegantly used to simultaneously react with a third species, resulting in unusual reactivity of small molecules. Such unusual reactions, explored only in the last few years, have found several applications, e.g., heterolytic splitting of H2, activation of small molecules (CO2, N2O, etc.). FLPs have opened new opportunities in synthetic chemistry, covering organic, main group as well as transition metal chemistry. The design strategies adopted for FLP systems and their unique reactivity are discussed here.
650			_aLewis acids _vLewis bases _xFrustrated lewis pairs
700	1		_aThilagar, Pakkirisamy _eauthor
856			_uhttps://doi.org/10.1007/s12039-015-0783-4
942			_2lcc _cJA
999			_c169251 _d169251