| 000 | 01494nam a22002417a 4500 | ||
|---|---|---|---|
| 003 | ZW-GwMSU | ||
| 005 | 20250311100113.0 | ||
| 008 | 250311b |||||||| |||| 00| 0 eng d | ||
| 022 | _a09743626 | ||
| 040 |
_aMSU _bEnglish _cMSU _erda |
||
| 050 | 0 | 0 | _aQD31 JOU |
| 100 | 1 |
_aBerry, John F. _eauthor |
|
| 245 | 1 | 0 |
_aMetal–metal multiple bonded intermediates in catalysis / _ccreated by John F. Berry |
| 264 | 1 |
_aBangalore : _bSprinter, _c2015. |
|
| 336 |
_2rdacontent _atext _btxt |
||
| 337 |
_2rdamedia _aunmediated _bn |
||
| 338 |
_2rdacarrier _avolume _bnc |
||
| 440 |
_aJournal of chemical sciences _vVolume 127, number 2, |
||
| 520 | 3 | _aMetal–metal bonded Rh2 and Ru2 complexes having a paddlewheel-type structure are exceptional catalysts for a broad range of organic transformations. I review here the recent efforts towards the observation and characterization of intermediates in these reactions that have previously eluded detection. Specifically, mechanistic investigations of carbenoid and nitrenoid reactions of Rh2(II,II)-tetracarboxylate compounds have led to the observation of a metastable Rh2(II,II) carbene complex as well as a mixed-valent Rh2(II,III)-amido intermediate. Related Ru2 nitrido compounds have been studied and found to undergo intramolecular C–H amination reactions as well as intermolecular reaction with triphenylphosphine. | |
| 650 |
_aCatalysis _vMetal-metal bonds _xCarbene |
||
| 856 | _uhttps://doi.org/10.1007/s12039-015-0773-6 | ||
| 942 |
_2lcc _cJA |
||
| 999 |
_c169243 _d169243 |
||