000 01502nam a22002537a 4500
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022 _a09743626
040 _aMSU
_bEnglish
_cMSU
_erda
050 0 0 _aQD31 JOU
100 1 _aMallick, Dibyendu
_eauthor
245 1 0 _aStructural variations in aromatic 2π-electron three-membered rings of the main group elements /
_ccreated by Dibyendu Mallick and Eluvathingal Jemmis
264 1 _aBangalore :
_bSprinter,
_c2015.
336 _2rdacontent
_atext
_btxt
337 _2rdamedia
_aunmediated
_bn
338 _2rdacarrier
_avolume
_bnc
440 _aJournal of chemical sciences
_vVolume 127, number 2,
520 3 _aStructural variations of different 2 π-aromatic three-membered ring systems of main group elements, especially group 14 and 13 elements as compared to the classical description of cyclopropenyl cation has been reviewed in this article. The structures of heavier analogues as well as group 13 analogues of cyclopropenyl cation showed an emergence of dramatic structural patterns which do not conform to the general norms of carbon chemistry. Isolobal analogies between the main group fragments have been efficiently used to explain the peculiarities observed in these three-membered ring systems.
650 _aThree-membered ring
_v2π-aromaticity
_xIsolobal analogy
700 1 _aJemmis, Eluvathingal
_eco author
856 _uhttps://doi.org/10.1007/s12039-015-0777-2
942 _2lcc
_cJA
999 _c169240
_d169240