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| 022 | _a09743626 | ||
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_aMSU _bEnglish _cMSU _erda |
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| 050 | 0 | 0 | _aQD31 JOU |
| 100 | 1 |
_aLobana, Tarlok S. _eauthor |
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| 245 | 1 | 0 |
_aReactivity of thiazolidine-2-thione towards CuI/CuII: Synthesis and structures of [3-(2-thiazolin-2-yl)thiazolidine-2-thione]copper(I) bromide and [bis(2,2′-bipyridine)nitratocopper(II)] nitrate / _ccreated by Tarlok S. Lobana, Anu Rani, Amanpreet Kaur Jassal and Jerry P. Jasinski |
| 264 | 1 |
_aBangalore : _bSpringer, _c2015. |
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| 336 |
_2rdacontent _atext _btxt |
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| 337 |
_2rdamedia _aunmediated _bn |
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| 338 |
_2rdacarrier _avolume _bnc |
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| 440 |
_aJournal of chemical sciences _vVolume 127, number 1, |
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| 520 | 3 | _aThiazolidine-2-thione (L1, NC3H5S2) reacted with copper(I) bromide in CH3CN under aerobic conditions and transformed through C–S bond cleavage into 3-(2-thiazolin-2-yl)thiazolidine-2-thione (L2, C3H4S2N-C3H4SN). This thio-ligand L2 with CuI ion yielded a three coordinate complex, [3-(2-Thiazolin-2-yl)thiazolidine-2-thione]copper(I)bromide 1a which crystallized in the triclinic system with the space group P1 as reported earlier. Treatment of 1a with bis(diphenylphosphino)methane (dppm) in dichloromethane also formed [3-(2-thiazolin-2-yl)thiazolidine-2-thione]copper(I) bromide 1b but it crystallized into the triclinic system with a new space group, P-1: 296(2) K, a, 7.3890(19); b, 8.473(2); c, 9.491(2) Å; α, 70.273(5); β, 67.170(5); γ, 84.949(5)∘; R, 6.79%. Reactions of copper(II) nitrate with thiazolidine-2-thione followed by the addition of 2,2′-bipyridine or with 2,2′-bipyridine first followed by the addition of thiazolidine-2-thione, gave blue crystals in both the cases. The x-ray crystallography revealed stoichiometry of the complex formed as: [Cu(κ 2-N,N′-bipy)2(κ 1-ONO2)](NO3)2, which crystallized in monoclinic crystal system with space group, P21/n(14). Crystal data: 173(2) K, a, 11.318(1), b, 12.160(1), c, 14.967(1) Å; β = 98.01(1)∘, R, 3.99%; 296(2) K, a, 11.340(5), b, 12.249(5), c, 15.065(6) Å; β = 98.04(2)∘, R, 4.09%. | |
| 650 |
_aThiazolidine-2-thione _v3-(2-thiazolin-2-yl)thiazolidine-2-thione _x2′-bipyridine |
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| 700 | 1 |
_aRani, Anu _eco author |
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| 700 | 1 |
_aKaur Jassal, Amanpreet _eco author |
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| 700 | 1 |
_aJasinski, Jerry P. _eco author |
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| 856 | _uhttps://doi.org/10.1007/s12039-014-0760-3 | ||
| 942 |
_2lcc _cJA |
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_c169229 _d169229 |
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