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040 _aMSU
_cMSU
_erda
100 _aMARZAL - ESPINOSA, Rosa M
245 _aImpact of in-pore salt crystallization on transport properties
264 _aVerlag
_bSpringer
_c2013
336 _2rdacontent
_atext
_btxt
337 _2rdamedia
_aunmediated
_bn
338 _2rdacarrier
_avolume
_bnc
440 _aEnvironmental earth science
_vVolume , number ,
520 _aPrecipitation of salts in confined spaces is the key mechanism for rock weathering and damage to building materials. To date there is no comprehensive study of the parameters influencing the reduction of pore space by salt crystals and the consequences for transport and damage by crystallization pressure. A novel method is presented to quantify pore clogging (i.e., the degree to which crystallization of salts interferes with transport of solution in porous materials). After drying capillary-saturated stone specimens containing salt solutions, the rate of capillary uptake of decane into the salt-contaminated specimens is measured. By treating the salt-contaminated material as a bilayer, the width of the crystallization front and the degree of pore filling can be determined. Two model materials with different pore size distributions (Indiana and Highmoor limestone) and three salts (sodium chloride, sodium sulfate and magnesium sulfate) are selected for this study. It is shown that pore clogging results from the interplay between pore size distribution and salt properties. Different scenarios are discussed to link pore clogging with salt damage.
650 _asalt weathering
650 _aore clogging
650 _acrystallization
700 _aSCHERER, George W.
856 _uhttps://doi.org/10.1007/s12665-012-2087-z
942 _2lcc
_cJA
999 _c160950
_d160950