Understanding distribution and abundance of metals with space and time in estuarine mudflat sedimentary environment

Spatial and depth-wise distribution of sediment components, organic carbon and selected metals (Fe, Mn, Al, Ni, Cr, Co, Zn and Pb) is studied across upper and middle tidal flats from lower and middle estuarine regions of Kundalika Estuary, central west coast of India. Silt and clay form the major components in lower and middle estuary, respectively. Sand, silt, clay and organic carbon showed band-type distribution along the estuary. The sediment deposition over the years took place in varying hydrodynamic conditions in lower and middle estuarine regions. Upper flats of the lower estuary represent mud while middle flats of the lower estuary facilitated the deposition of sandy mud. Correlation results indicated the importance of clay and organic carbon in removal and trapping of metals at lower and middle estuary, respectively. Factor analysis indicated that the distribution of metals is largely controlled by Fe–Mn oxyhydroxides and organic carbon. The middle flats of the lower estuary showed an anthropogenic source for Ni, Cr and Co while middle flats of the middle estuary showed a mainly lithogenic source.