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Efficient iron(III) porphyrins-catalyzed oxidation of guanidoximes to cyanamides in ionic liquids / created by P. Kumari, Ritika Nagpal, P. Chauhan, Vinith Yatindranath, S. M. Chauhan

By: Contributor(s): Material type: TextTextSeries: Journal of chemical sciences ; Volume 127, number 1,Bangalore : Springer, 2015Content type:
  • text
Media type:
  • unmediated
Carrier type:
  • volume
ISSN:
  • 09743626
Subject(s): LOC classification:
  • QD31 JOU
Online resources: Abstract: Water soluble iron(III) porphyrins immobilized in imidazolium ionic liquids serve as an effective catalyst for the H2O2 mediated oxidation of guanidoximes to selectively give corresponding cyanamides in good yields. The use of ionic liquid with non-coordinating counter anion PF6 affords the product in high yield by facilitating the formation of anionic iron peroxo intermediate.
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Item type Current library Call number Vol info Status Notes Date due Barcode
Journal Article Journal Article Main Library - Special Collections QD31 JOU (Browse shelf(Opens below)) Vol. 127, no.1 (pages13-18) Not for loan For in house use only

Water soluble iron(III) porphyrins immobilized in imidazolium ionic liquids serve as an effective catalyst for the H2O2 mediated oxidation of guanidoximes to selectively give corresponding cyanamides in good yields. The use of ionic liquid with non-coordinating counter anion PF6 affords the product in high yield by facilitating the formation of anionic iron peroxo intermediate.

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