TY  - BOOK
AU  - Lu,Yanju
AU  - Wang,Mixia
AU  - Zhao,Zhendong
AU  - Chen,Yuxiang
AU  - Wang,Shichao XuJing
AU  - Bi,Liangwu
TI  - Facile synthesis of allyl resinate monomer in an aqueous solution under microwave irradiation
SN  - 09743626
AV  - QD31 JOU 
PY  - 2015///
CY  - Bangalore
PB  - Springer
KW  - Allyl resinate
KW  - Microwave energy
KW  - Rosin-derivatives
N2  - We have developed a facile method for production of allyl resinate monomer (allyl rosin ester) via a phase transfer reaction under microwave irradiation. The synthesis of allyl resinate was conducted using allyl chloride and sodium resinate as starting materials in aqueous solution at 50° for 30 min with a yield of 94.7%, which is 20% higher than conventional heating method. The products precipitated spontaneously from the aqueous phase after reaction, which significantly facilitated the subsequent separation of monomer products. The synthesized monomer product appeared as a viscous liquid, with a viscosity of 460 mPa ⋅s at 25° and a density of 1.0469 g/cm3. The physical and chemical properties suggested that the synthesized monomer has great potential for free radical polymerization
UR  - https://doi.org/10.1007/s12039-015-0879-x
ER  -