Hydrothermal synthesis, crystal structure and luminescence property of a three dimensional Sm(III) coordination polymer with 2,5-pyridinedicarboxylic acid / created by Kranthi Kumar Gangu, Anima S Dadhich and Saratchandra Babu Mukkamala

By:

Gangu, Kranthi Kumar [author]

Contributor(s):

Material type: Text

TextSeries: Journal Of chemical sciences ; Volume 127, number 12,Bangalore : Springer, 2015Content type:

text

Media type:

unmediated

Carrier type:

volume

ISSN:

09743626

Subject(s):

Hydrothermal synthesis -- Coordination polymer -- X-ray diffraction

LOC classification:

QD31 JOU

Online resources:

Click here to access online

Abstract: A novel three dimensional coordination polymer [Sm(2,5-pydc)(NO3)(H2O)] ⋅(H2O) (2,5-pydc = 2,5-pyridine dicarboxylate) (1) had been synthesized hydrothermally and characterized by elemental analysis, FT-IR and single-crystal X-ray diffraction analysis. This coordination polymer crystallized in the monoclinic space group P2/n with cell parameters a= 9.3610(4) Å, b= 8.3498(3) Å, c= 16.7159(8) Å, β= 106.31(0)∘, V= 1253.98(184) Å3. Thermogravimetric analysis revealed that complex 1 is stable up to 400∘C which on photoexcitation at 365 nm exhibited yellow emission at 583 nm.

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Item type	Current library	Call number	Vol info	Status	Notes	Date due	Barcode
Journal Article	Main Library - Special Collections	QD31 JOU (Browse shelf(Opens below))	Vol. 127, no.12 (2225-2230)	Not for loan	For in house use only

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A novel three dimensional coordination polymer [Sm(2,5-pydc)(NO3)(H2O)] ⋅(H2O) (2,5-pydc = 2,5-pyridine dicarboxylate) (1) had been synthesized hydrothermally and characterized by elemental analysis, FT-IR and single-crystal X-ray diffraction analysis. This coordination polymer crystallized in the monoclinic space group P2/n with cell parameters a= 9.3610(4) Å, b= 8.3498(3) Å, c= 16.7159(8) Å, β= 106.31(0)∘, V= 1253.98(184) Å3. Thermogravimetric analysis revealed that complex 1 is stable up to 400∘C which on photoexcitation at 365 nm exhibited yellow emission at 583 nm.

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