A comparative study of Cu(II)-assisted vs Cu(II)-free chalcogenation on benzyl and 2°/3°-cycloalkyl moieties / created by Santosh K. Sahoo

By:

Sahoo, Santosh K [author]

Material type: Text

TextSeries: Journal of chemical sciences ; Volume 127, number 12,Bangalore : Springer, 2015Content type:

text

Media type:

unmediated

Carrier type:

volume

ISSN:

09743626

Subject(s):

C-H functionalization -- C-Chalcogen bond formation -- Metal vs. metal free condition

LOC classification:

QD31 JOU

Online resources:

Click here to access online

Abstract: A relative synthetic strategy toward intermolecular oxidative C −Chalcogen bond formation of alkanes has been illustrated using both Cu(II) assisted vs Cu(II) free conditions. This led to construction of a comparative study of hydrocarbon benzylic and 2∘/ 3∘-cycloalkyl moieties bond sulfenylation and selenation protocol by the chalcogen sources, particularly sulfur and selenium, respectively. In addition, this protocol disclosed the auspicious formation of sp3 C−S coupling products over leading the sp3 C−N coupling products by using 2-mercaptobenzothiazole (MBT) substrates.

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Holdings
Item type	Current library	Call number	Vol info	Status	Notes	Date due	Barcode
Journal Article	Main Library - Special Collections	QD31 JOU (Browse shelf(Opens below))	Vol. 127, no.12 (pages 2151-2157)	Not for loan	For in house use only

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A relative synthetic strategy toward intermolecular oxidative C −Chalcogen bond formation of alkanes has been illustrated using both Cu(II) assisted vs Cu(II) free conditions. This led to construction of a comparative study of hydrocarbon benzylic and 2∘/ 3∘-cycloalkyl moieties bond sulfenylation and selenation protocol by the chalcogen sources, particularly sulfur and selenium, respectively. In addition, this protocol disclosed the auspicious formation of sp3 C−S coupling products over leading the sp3 C−N coupling products by using 2-mercaptobenzothiazole (MBT) substrates.

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