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A novel fluorescent turn-on probe for bisulfite based on NBD chromophore / created by Puhui Xie, Guangqin Gao, Wenjie Zhang, Guoyu Yang and Qiu Jin

By: Contributor(s): Material type: TextTextSeries: Journal of chemical sciences ; Volume 127, number 7,Bangalore : Springer, 2015Content type:
  • text
Media type:
  • unmediated
Carrier type:
  • volume
ISSN:
  • 09743626
Subject(s): LOC classification:
  • QD31 JOU
Online resources: Abstract: A novel fluorescent turn-on probe (compound 1) for bisulfite based on 7-nitrobenz-2-oxa-1,3-diazole (NBD) chromophore has been developed. Its sensing behavior toward various anions was investigated by absorption and fluorescence techniques. This probe shows a selective, turn-on fluorescent response and ratiometric colorimetric response toward bisulfite in aqueous acetonitrile solutions. The possible recognition mechanism of probe 1toward bisulfite was illustrated by MS spectra analysis and DFT calculations Probe 1 was used to determine bisulfite in real-life samples with good recoveries.
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A novel fluorescent turn-on probe (compound 1) for bisulfite based on 7-nitrobenz-2-oxa-1,3-diazole (NBD) chromophore has been developed. Its sensing behavior toward various anions was investigated by absorption and fluorescence techniques. This probe shows a selective, turn-on fluorescent response and ratiometric colorimetric response toward bisulfite in aqueous acetonitrile solutions. The possible recognition mechanism of probe 1toward bisulfite was illustrated by MS spectra analysis and DFT calculations Probe 1 was used to determine bisulfite in real-life samples with good recoveries.

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