Syntheses of fused tetrahydro-β-carboline analogues through imide carbonyl activation using BBr3 : evidence for the involvement of fused cyclic N-acyliminium ion intermediate / created by S. Mangalaraj, J. Selvakumar and C. Ramanathan

By:

Mangalaraj, S [author]

Contributor(s):

Material type: Text

TextSeries: Journal of chemical sciences ; Volume 127, number 5,Bangalore : Springer, 2015Content type:

text

Media type:

unmediated

Carrier type:

volume

ISSN:

09743626

Subject(s):

Intramolecular cyclization -- Fused cyclic N-acyliminium ion -- Tetrahydro-β-carboline

LOC classification:

QD31 JOU

Online resources:

Click here to access online

Abstract: The fused cyclic N-acyliminium ion generated during the imide carbonyl activation reaction of phenethylphthalimide was confirmed by single crystal X-ray diffraction. The Lewis acid assisted imide carbonyl activation methodology was successfully extended to synthesize fused tetrahydro-β-carboline units from the corresponding N-indolylethylimides.

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Item type	Current library	Call number	Vol info	Status	Notes	Date due	Barcode
Journal Article	Main Library - Special Collections	QD31 JOU (Browse shelf(Opens below))	Vol. 127, no.5 (pages 811-819)	Not for loan	For in house use only

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The fused cyclic N-acyliminium ion generated during the imide carbonyl activation reaction of phenethylphthalimide was confirmed by single crystal X-ray diffraction. The Lewis acid assisted imide carbonyl activation methodology was successfully extended to synthesize fused tetrahydro-β-carboline units from the corresponding N-indolylethylimides.

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