MARC details
| 000 -LEADER |
|---|
| fixed length control field |
01991nam a22002537a 4500 |
| 003 - CONTROL NUMBER IDENTIFIER |
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| control field |
ZW-GwMSU |
| 005 - DATE AND TIME OF LATEST TRANSACTION |
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| control field |
20250319082959.0 |
| 008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION |
|---|
| fixed length control field |
250319b |||||||| |||| 00| 0 eng d |
| 022 ## - INTERNATIONAL STANDARD SERIAL NUMBER |
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| International Standard Serial Number |
09743626 |
| 040 ## - CATALOGING SOURCE |
|---|
| Original cataloging agency |
MSU |
| Language of cataloging |
English |
| Transcribing agency |
MSU |
| Description conventions |
rda |
| 050 00 - LIBRARY OF CONGRESS CALL NUMBER |
|---|
| Classification number |
QD31 JOU |
| 100 1# - MAIN ENTRY--PERSONAL NAME |
|---|
| Personal name |
Ghosh, Tulika |
| Relator term |
author |
| 245 10 - TITLE STATEMENT |
|---|
| Title |
Synthesis and characterization of dodecahedral cerium(IV) and gadolinium(III) complexes with a tetradentate Schiff Base / |
| Statement of responsibility, etc. |
created by Tulika Ghosh and Samudranil Pal |
| 264 1# - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE |
|---|
| Place of production, publication, distribution, manufacture |
Bangalore : |
| Name of producer, publisher, distributor, manufacturer |
Springer, |
| Date of production, publication, distribution, manufacture, or copyright notice |
2015. |
| 336 ## - CONTENT TYPE |
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| Source |
rdacontent |
| Content type term |
text |
| Content type code |
txt |
| 337 ## - MEDIA TYPE |
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| Source |
rdamedia |
| Media type term |
unmediated |
| Media type code |
n |
| 338 ## - CARRIER TYPE |
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| Source |
rdacarrier |
| Carrier type term |
volume |
| Carrier type code |
nc |
| 440 ## - SERIES STATEMENT/ADDED ENTRY--TITLE |
|---|
| Title |
Journal of chemical sciences |
| Volume/sequential designation |
Volume 127, number 7, |
| 520 3# - SUMMARY, ETC. |
|---|
| Summary, etc. |
Reactions of CeCl3⋅6H2O and Gd(NO3)3⋅5H2O with biacetyl bis(benzoylhydrazone) (H2babh) and KOH in 1:2:2 mole ratio in methanol afford the complexes [Ce(babh)2] (1) and [Gd(babh)(Hbabh)]⋅H2O (2⋅H2O), respectively in good yields. Characterization of the complexes has been performed with the help of elemental analysis, magnetic susceptibility, spectroscopic (IR, UV-Vis, EPR and NMR) and X-ray crystallographic measurements. 1 is diamagnetic and NMR active, while 2⋅H2O is paramagnetic (μ eff = 8.03 μ B at 300 K) and EPR active. The complexes crystallize as 1⋅CH2Cl2 and 2⋅H2O. X-ray structures show that the metal centre in each of 1 and 2 is in a distorted dodecahedral N4O4 coordination sphere assembled by two meridionally spanning ONNO-donor ligands. Self-assembly of 1⋅CH2Cl2 via intermolecular C−H⋯N and C−H⋯Cl hydrogen bonds and π- π interactions provides one-dimensional ‘ladder’ type structure. On the other hand, 2⋅H2O assembles into a two-dimensional ‘sheet’ like network through intermolecular N−H⋯O and O−H⋯N hydrogen bonds. |
| 650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM |
|---|
| Topical term or geographic name entry element |
Cerium(IV) |
| Form subdivision |
Gadolinium(III) |
| General subdivision |
Tetradentate ligand |
| 700 1# - ADDED ENTRY--PERSONAL NAME |
|---|
| Personal name |
Pal, Samudranil |
| Relator term |
co author |
| 856 ## - ELECTRONIC LOCATION AND ACCESS |
|---|
| Uniform Resource Identifier |
https://doi.org/10.1007/s12039-015-0887-x |
| 942 ## - ADDED ENTRY ELEMENTS (KOHA) |
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| Source of classification or shelving scheme |
Library of Congress Classification |
| Koha item type |
Journal Article |