Midlands State University Library

Syntheses, structures and luminescence behaviour of some zinc(II) complexes containing acetate and tetradentate Schiff bases / (Record no. 169323)

MARC details
000 -LEADER
fixed length control field 02354nam a22002897a 4500
003 - CONTROL NUMBER IDENTIFIER
control field ZW-GwMSU
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250318071525.0
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 250318b |||||||| |||| 00| 0 eng d
022 ## - INTERNATIONAL STANDARD SERIAL NUMBER
International Standard Serial Number 09743626
040 ## - CATALOGING SOURCE
Original cataloging agency MSU
Language of cataloging English
Transcribing agency MSU
Description conventions rda
050 00 - LIBRARY OF CONGRESS CALL NUMBER
Classification number QD31 JOU
100 1# - MAIN ENTRY--PERSONAL NAME
Personal name Maji, Ashis Kumar
Relator term author
245 10 - TITLE STATEMENT
Title Syntheses, structures and luminescence behaviour of some zinc(II) complexes containing acetate and tetradentate Schiff bases /
Statement of responsibility, etc. created by Ashis Kumar Maji, Subhasis Roy, Somnath Choubey, Rajarshi Ghosh and Barindra Kumar Ghosh
264 1# - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE
Place of production, publication, distribution, manufacture Bangalore :
Name of producer, publisher, distributor, manufacturer Springer,
Date of production, publication, distribution, manufacture, or copyright notice 2015.
336 ## - CONTENT TYPE
Source rdacontent
Content type term text
Content type code txt
337 ## - MEDIA TYPE
Source rdamedia
Media type term unmediated
Media type code n
338 ## - CARRIER TYPE
Source rdacarrier
Carrier type term volume
Carrier type code nc
440 ## - SERIES STATEMENT/ADDED ENTRY--TITLE
Title Journal of chemical sciences
Volume/sequential designation Volume 127, number 5,
520 3# - SUMMARY, ETC.
Summary, etc. Two mononuclear compounds of the types pentacoordinated [Zn(L1)(OAc)]PF6⋅H2O (1) and hexacoordinated [Zn(L2)(OAc)]PF6 (2) [L1 = N,N -(bis(pyridin-2-yl)formylidene)-1,3-propanediamine; L2 = N,N -(bis(pyridin-2-yl)benzylidene)-1,4-butanediamine] have been synthesized using one-pot reactions of a 1:1:1 molar ratio of Zn(OAc)2.2H2O, L1/L2, ammonium hexafluorophosphate in MeOH at room temperature. Compounds 1 and 2 are characterized on the basis of microanalytical, spectroscopic, thermal and other physicochemical results. Single crystal X-ray structural study reveals that the zinc(II) centre in 1 is coordinated by four N atoms of the Schiff base L1 and one O atom of terminal acetate with a ZnN4O chromophore, whereas in 2, the zinc(II) centre is bound by four N atoms of the tailored Schiff base L2 and two O atoms of the chelated acetate. In the crystalline state, mononuclear units in 1 are engaged in weak cooperative intermolecular O-H ⋯O and C-H ⋯F hydrogen bonds affording a 1D chain. The individual units of 2 are packed by π⋯π and anion ⋯π interactions to form a 2D sheet structure. The complexes show reasonable thermal stabilities and display intraligand π→π ∗ fluorescence in solid state at room temperature.
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Mononuclear zinc(II)
Form subdivision Schiff base
General subdivision Versatile acetate
700 1# - ADDED ENTRY--PERSONAL NAME
Personal name Roy, Subhasis
Relator term co author
700 1# - ADDED ENTRY--PERSONAL NAME
Personal name Choubey, Somnath
Relator term co author
700 1# - ADDED ENTRY--PERSONAL NAME
Personal name Ghosh, Rajarshi
Relator term co author
700 1# - ADDED ENTRY--PERSONAL NAME
Personal name Ghosh, Barindra Kumar
Relator term co author
856 ## - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier https://doi.org/10.1007/s12039-015-0842-x
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Source of classification or shelving scheme Library of Congress Classification
Koha item type Journal Article
Holdings
Withdrawn status Lost status Source of classification or shelving scheme Damaged status Not for loan Home library Current library Shelving location Date acquired Serial Enumeration / chronology Total Checkouts Full call number Date last seen Price effective from Koha item type Public note
    Library of Congress Classification     Main Library Main Library - Special Collections 02/10/2015 Vol. 127, no.5 (pages 865-872)   QD31 JOU 18/03/2025 18/03/2025 Journal Article For in house use only