MARC details
000 -LEADER |
fixed length control field |
02354nam a22002897a 4500 |
003 - CONTROL NUMBER IDENTIFIER |
control field |
ZW-GwMSU |
005 - DATE AND TIME OF LATEST TRANSACTION |
control field |
20250318071525.0 |
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION |
fixed length control field |
250318b |||||||| |||| 00| 0 eng d |
022 ## - INTERNATIONAL STANDARD SERIAL NUMBER |
International Standard Serial Number |
09743626 |
040 ## - CATALOGING SOURCE |
Original cataloging agency |
MSU |
Language of cataloging |
English |
Transcribing agency |
MSU |
Description conventions |
rda |
050 00 - LIBRARY OF CONGRESS CALL NUMBER |
Classification number |
QD31 JOU |
100 1# - MAIN ENTRY--PERSONAL NAME |
Personal name |
Maji, Ashis Kumar |
Relator term |
author |
245 10 - TITLE STATEMENT |
Title |
Syntheses, structures and luminescence behaviour of some zinc(II) complexes containing acetate and tetradentate Schiff bases / |
Statement of responsibility, etc. |
created by Ashis Kumar Maji, Subhasis Roy, Somnath Choubey, Rajarshi Ghosh and Barindra Kumar Ghosh |
264 1# - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE |
Place of production, publication, distribution, manufacture |
Bangalore : |
Name of producer, publisher, distributor, manufacturer |
Springer, |
Date of production, publication, distribution, manufacture, or copyright notice |
2015. |
336 ## - CONTENT TYPE |
Source |
rdacontent |
Content type term |
text |
Content type code |
txt |
337 ## - MEDIA TYPE |
Source |
rdamedia |
Media type term |
unmediated |
Media type code |
n |
338 ## - CARRIER TYPE |
Source |
rdacarrier |
Carrier type term |
volume |
Carrier type code |
nc |
440 ## - SERIES STATEMENT/ADDED ENTRY--TITLE |
Title |
Journal of chemical sciences |
Volume/sequential designation |
Volume 127, number 5, |
520 3# - SUMMARY, ETC. |
Summary, etc. |
Two mononuclear compounds of the types pentacoordinated [Zn(L1)(OAc)]PF6⋅H2O (1) and hexacoordinated [Zn(L2)(OAc)]PF6 (2) [L1 = N,N -(bis(pyridin-2-yl)formylidene)-1,3-propanediamine; L2 = N,N -(bis(pyridin-2-yl)benzylidene)-1,4-butanediamine] have been synthesized using one-pot reactions of a 1:1:1 molar ratio of Zn(OAc)2.2H2O, L1/L2, ammonium hexafluorophosphate in MeOH at room temperature. Compounds 1 and 2 are characterized on the basis of microanalytical, spectroscopic, thermal and other physicochemical results. Single crystal X-ray structural study reveals that the zinc(II) centre in 1 is coordinated by four N atoms of the Schiff base L1 and one O atom of terminal acetate with a ZnN4O chromophore, whereas in 2, the zinc(II) centre is bound by four N atoms of the tailored Schiff base L2 and two O atoms of the chelated acetate. In the crystalline state, mononuclear units in 1 are engaged in weak cooperative intermolecular O-H ⋯O and C-H ⋯F hydrogen bonds affording a 1D chain. The individual units of 2 are packed by π⋯π and anion ⋯π interactions to form a 2D sheet structure. The complexes show reasonable thermal stabilities and display intraligand π→π ∗ fluorescence in solid state at room temperature. |
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM |
Topical term or geographic name entry element |
Mononuclear zinc(II) |
Form subdivision |
Schiff base |
General subdivision |
Versatile acetate |
700 1# - ADDED ENTRY--PERSONAL NAME |
Personal name |
Roy, Subhasis |
Relator term |
co author |
700 1# - ADDED ENTRY--PERSONAL NAME |
Personal name |
Choubey, Somnath |
Relator term |
co author |
700 1# - ADDED ENTRY--PERSONAL NAME |
Personal name |
Ghosh, Rajarshi |
Relator term |
co author |
700 1# - ADDED ENTRY--PERSONAL NAME |
Personal name |
Ghosh, Barindra Kumar |
Relator term |
co author |
856 ## - ELECTRONIC LOCATION AND ACCESS |
Uniform Resource Identifier |
https://doi.org/10.1007/s12039-015-0842-x |
942 ## - ADDED ENTRY ELEMENTS (KOHA) |
Source of classification or shelving scheme |
Library of Congress Classification |
Koha item type |
Journal Article |