MARC details
| 000 -LEADER |
|---|
| fixed length control field |
02700nam a22002777a 4500 |
| 003 - CONTROL NUMBER IDENTIFIER |
|---|
| control field |
ZW-GwMSU |
| 005 - DATE AND TIME OF LATEST TRANSACTION |
|---|
| control field |
20250317143156.0 |
| 008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION |
|---|
| fixed length control field |
250317b |||||||| |||| 00| 0 eng d |
| 022 ## - INTERNATIONAL STANDARD SERIAL NUMBER |
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| International Standard Serial Number |
09743626 |
| 040 ## - CATALOGING SOURCE |
|---|
| Original cataloging agency |
MSU |
| Language of cataloging |
English |
| Transcribing agency |
MSU |
| Description conventions |
rda |
| 050 00 - LIBRARY OF CONGRESS CALL NUMBER |
|---|
| Classification number |
QD31 JOU |
| 100 1# - MAIN ENTRY--PERSONAL NAME |
|---|
| Personal name |
Mudsainiyan, R. K. |
| Relator term |
author |
| 245 10 - TITLE STATEMENT |
|---|
| Title |
Synthesis, crystal structure determination of two-dimensional supramolecular co-ordination polymer of silver(I) with 1,2-Bis(phenylthio)ethane and its Hirshfeld surface analysis / |
| Statement of responsibility, etc. |
created by R. K. Mudsainiyan, A. K. Jassal, Meenu Arora and S. Chawla |
| 264 1# - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE |
|---|
| Place of production, publication, distribution, manufacture |
Bangalore : |
| Name of producer, publisher, distributor, manufacturer |
Springer, |
| Date of production, publication, distribution, manufacture, or copyright notice |
2015. |
| 336 ## - CONTENT TYPE |
|---|
| Source |
rdacontent |
| Content type term |
text |
| Content type code |
txt |
| 337 ## - MEDIA TYPE |
|---|
| Source |
rdamedia |
| Media type term |
unmediated |
| Media type code |
n |
| 338 ## - CARRIER TYPE |
|---|
| Source |
rdacarrier |
| Carrier type term |
volume |
| Carrier type code |
nc |
| 440 ## - SERIES STATEMENT/ADDED ENTRY--TITLE |
|---|
| Title |
Journal of chemical sciences |
| Volume/sequential designation |
Volume 127, number 5, |
| 520 3# - SUMMARY, ETC. |
|---|
| Summary, etc. |
The 2-D polymeric complex (I) has the formula [ A g ( p h S E ) ( N O 3 )] n , which has been crystallized from methanol-acetonitrile mixture and characterized by elemental analysis and single-crystal X-ray diffraction analysis. In this polymer, each Ag(I) ion occupies distorted trigonal pyramidal geometry coordinating with two sulphur atoms from two different ligands and two oxygen atoms from two NO3 groups. Each NO3 acts as a bridging ligand coordinating through its two oxygen atoms to different Ag(I) ions. The Ag(I) ion and NO3 group are in plane with torsion angle 176.43∘. All the ligands adopt anti-conformation but the relative orientation of two -S-C-C-S units is perpendicular to one another such that two phenyl rings attached to the two sulphur atoms coordinating to a particular Ag ion lie on the same side. Each NO3 bridges two neighbouring Ag ions belonging to two different -S-Ag-S-C-C-S-Ag-S- tapes running along a-axis where two phenyl rings are not parallel to each other to reduce the steric hindrance and maximize packing. The adjacent chains are fused to form 2D sheet by bridging both through bidentate phSE ligand and NO3 anion stacking in ab plane. The structure consists of 4-c uninodal net where Point symbol for Ag (I) ion and net is (44.62) with sql type topology. X-ray diffraction analysis and Hirshfeld surface analysis give rise to comparable results but in Hirshfeld surface analysis, two-third times more close contacts are obtained. The fingerprint plots demonstrate that these weak non-bonding interactions are important for stabilizing the crystal packing. |
| 650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM |
|---|
| Topical term or geographic name entry element |
Distorted trigonal pyramidal geometry |
| Form subdivision |
Anti-conformation |
| General subdivision |
Steric hindrance |
| 700 1# - ADDED ENTRY--PERSONAL NAME |
|---|
| Personal name |
Jassal, A. K. |
| Relator term |
co author |
| 700 1# - ADDED ENTRY--PERSONAL NAME |
|---|
| Personal name |
Arora, Meenu |
| Relator term |
co author |
| 700 1# - ADDED ENTRY--PERSONAL NAME |
|---|
| Personal name |
Chawla, S. |
| Relator term |
co author |
| 856 ## - ELECTRONIC LOCATION AND ACCESS |
|---|
| Uniform Resource Identifier |
https://doi.org/10.1007/s12039-015-0839-5 |
| 942 ## - ADDED ENTRY ELEMENTS (KOHA) |
|---|
| Source of classification or shelving scheme |
Library of Congress Classification |
| Koha item type |
Journal Article |