MARC details
| 000 -LEADER |
|---|
| fixed length control field |
02011nam a22002537a 4500 |
| 003 - CONTROL NUMBER IDENTIFIER |
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| control field |
ZW-GwMSU |
| 005 - DATE AND TIME OF LATEST TRANSACTION |
|---|
| control field |
20250317074624.0 |
| 008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION |
|---|
| fixed length control field |
250317b |||||||| |||| 00| 0 eng d |
| 022 ## - INTERNATIONAL STANDARD SERIAL NUMBER |
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| International Standard Serial Number |
09743626 |
| 040 ## - CATALOGING SOURCE |
|---|
| Original cataloging agency |
MSU |
| Language of cataloging |
English |
| Transcribing agency |
MSU |
| Description conventions |
rda |
| 050 00 - LIBRARY OF CONGRESS CALL NUMBER |
|---|
| Classification number |
QD31 JOU |
| 100 1# - MAIN ENTRY--PERSONAL NAME |
|---|
| Personal name |
Prashanth, Billa |
| Relator term |
author |
| 245 10 - TITLE STATEMENT |
|---|
| Title |
Bulky iminophosphonamines for N–P–N coordination : |
| Remainder of title |
synthesis and structural characterization of lithium iminophosphonamides and homoleptic bis-chelates of Co(II), Ni(II) and Cu(II) / |
| Statement of responsibility, etc. |
created by Billa Prashanth and Sanjay Singh |
| 264 1# - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE |
|---|
| Place of production, publication, distribution, manufacture |
Bangalore : |
| Name of producer, publisher, distributor, manufacturer |
Springer, |
| Date of production, publication, distribution, manufacture, or copyright notice |
2015. |
| 336 ## - CONTENT TYPE |
|---|
| Source |
rdacontent |
| Content type term |
text |
| Content type code |
txt |
| 337 ## - MEDIA TYPE |
|---|
| Source |
rdamedia |
| Media type term |
unmediated |
| Media type code |
n |
| 338 ## - CARRIER TYPE |
|---|
| Source |
rdacarrier |
| Carrier type term |
volume |
| Carrier type code |
nc |
| 440 ## - SERIES STATEMENT/ADDED ENTRY--TITLE |
|---|
| Title |
Journal of chemical sciences |
| Volume/sequential designation |
Volume 127, number 2, |
| 520 3# - SUMMARY, ETC. |
|---|
| Summary, etc. |
Two new sterically demanding iminophosphonamine ligands (2,4,6-Me3C6H2NH)P(Ph 2)=N (C6H2-2,4,6-Me3)(1) and (2,6-iPr2C6H3NH)P(Ph2)=N(C6H2-2,4,6-Me3) (2) and their lithium derivatives as tmeda adducts (Li ⋅tmeda)[(2,4,6-Me3C6H2)NP(Ph2)=N(C6H2-2,4,6-Me3)] (3) and (Li ⋅tmeda)[(2,6-iPr2C6H3)NP(Ph2)=N(C6H2-2,4,6-Me3)] (4), respectively are reported here. Compounds 1–4 have been investigated by 1H, 13C and 13 P{1H} NMR spectroscopy. The 7Li NMR for complexes 3 and 4 has also been reported. Utility of the ligands and their lithium derivatives have been shown in the synthesis of bis-homoleptic metal complexes M[Ph2P(NC6H2-2,4,6-Me3)2]2 (M = Co (5), Cu (6) and Ni (7). Metal-bis-silylamide generated in situ was reacted with the ligand (for 5 and 6) or the lithium derivative of the ligand was reacted with the metal chloride (for 7). Molecular structure of compounds 1–7 has been elucidated by single crystal X-ray diffraction analyses. The complexes are formed in good yields and are highly lipophilic in a wide range of solvents. |
| 650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM |
|---|
| Topical term or geographic name entry element |
Metallacycles |
| Form subdivision |
Monoanion |
| General subdivision |
Homoleptic complexes |
| 700 1# - ADDED ENTRY--PERSONAL NAME |
|---|
| Personal name |
Singh, Sanjay |
| Relator term |
co author |
| 856 ## - ELECTRONIC LOCATION AND ACCESS |
|---|
| Uniform Resource Identifier |
https://doi.org/10.1007/s12039-015-0769-2 |
| 942 ## - ADDED ENTRY ELEMENTS (KOHA) |
|---|
| Source of classification or shelving scheme |
Library of Congress Classification |
| Koha item type |
Journal Article |