Midlands State University Library

Exploration of the structural features and magnetic behaviour in a novel 3-dimensional interpenetrating Co(II)-based framework / (Record no. 169253)

MARC details
000 -LEADER
fixed length control field 02112nam a22002657a 4500
003 - CONTROL NUMBER IDENTIFIER
control field ZW-GwMSU
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250311141806.0
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 250311b |||||||| |||| 00| 0 eng d
022 ## - INTERNATIONAL STANDARD SERIAL NUMBER
International Standard Serial Number 09743626
040 ## - CATALOGING SOURCE
Original cataloging agency MSU
Language of cataloging English
Transcribing agency MSU
Description conventions rda
050 00 - LIBRARY OF CONGRESS CALL NUMBER
Classification number QD31 JOU
100 1# - MAIN ENTRY--PERSONAL NAME
Personal name Goswami, Soumyabrata
Relator term author
245 10 - TITLE STATEMENT
Title Exploration of the structural features and magnetic behaviour in a novel 3-dimensional interpenetrating Co(II)-based framework /
Statement of responsibility, etc. created by Soumyabrata Goswami, A. Mondal, Sanjit Konar
264 1# - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE
Place of production, publication, distribution, manufacture Bangalore :
Name of producer, publisher, distributor, manufacturer Springer,
Date of production, publication, distribution, manufacture, or copyright notice 2015.
336 ## - CONTENT TYPE
Source rdacontent
Content type term text
Content type code txt
337 ## - MEDIA TYPE
Source rdamedia
Media type term unmediated
Media type code n
338 ## - CARRIER TYPE
Source rdacarrier
Carrier type term volume
Carrier type code nc
440 ## - SERIES STATEMENT/ADDED ENTRY--TITLE
Title Journal of chemical sciences
Volume/sequential designation Volume 127, number 2,
520 3# - SUMMARY, ETC.
Summary, etc. A new Co(II)-based three-dimensional (3D) framework having the molecular formula [Co(C4O4)(4-bpmh))H2O)2]n·2nH2O·2nMeOH·(1) (4-bpmh=N, N-bis-pyridin-4-ylmethylene-hydrazine) has been syn-thesized using a mixed ligand system and characterized by elemental analysis, IR spectroscopy, thermogravi-metric analysis, single crystal X-ray diffraction and variable temperature magnetic study. The framework isconstructed by the bridging squarate (C4O2−4)and N, N-bis-pyridin-4-ylmethylene-hydrazine (4-bpmh) ligandsand interpenetration of the 2D grid-like frameworks at definite angles gives rise to 2D→3D inclined polycate-nation with sql/Shubnikov tetragonal plane net topology. Extensive non-covalent interactions (H-bonding aswell asπ···πinteractions) are also observed which stabilises the 3D arrangement. Additionally, complex1contains 1D channels of large dimensions (10.91×11.78 Å2)that runs along theb-axis. Variable temperatureDC magnetic susceptibility study reveals dominant spin–orbit coupling effect typical of the4T1gground stateof octahedral high-spin Co(II) ion at a higher temperature range.
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Mixed ligand system
Form subdivision Co(II)-based 3D framework
General subdivision Interpenetrated structure
700 1# - ADDED ENTRY--PERSONAL NAME
Personal name Mondal, A.
Relator term co author
700 1# - ADDED ENTRY--PERSONAL NAME
Personal name Konar, Sanjit
Relator term co author
856 ## - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier https://doi.org/10.1007/s12039-015-0771-8
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Source of classification or shelving scheme Library of Congress Classification
Koha item type Journal Article
Holdings
Withdrawn status Lost status Source of classification or shelving scheme Damaged status Not for loan Home library Current library Shelving location Date acquired Serial Enumeration / chronology Total Checkouts Full call number Date last seen Price effective from Koha item type Public note
    Library of Congress Classification     Main Library Main Library - Special Collections 02/10/2015 Vol. 127, no.2 (pages 257-264)   QD31 JOU 11/03/2025 11/03/2025 Journal Article For in house use only