Midlands State University Library

Interesting cationic (Li+/Fe3+/Te6+) variations in new rocksalt ordered structures / (Record no. 169246)

MARC details
000 -LEADER
fixed length control field 02098nam a22002657a 4500
003 - CONTROL NUMBER IDENTIFIER
control field ZW-GwMSU
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250311102738.0
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 250311b |||||||| |||| 00| 0 eng d
022 ## - INTERNATIONAL STANDARD SERIAL NUMBER
International Standard Serial Number 09743626
040 ## - CATALOGING SOURCE
Original cataloging agency MSU
Language of cataloging English
Transcribing agency MSU
Description conventions rda
050 00 - LIBRARY OF CONGRESS CALL NUMBER
Classification number QD31 JOU
100 1# - MAIN ENTRY--PERSONAL NAME
Personal name Gupta, Akanksha
Relator term author
245 10 - TITLE STATEMENT
Title Interesting cationic (Li+/Fe3+/Te6+) variations in new rocksalt ordered structures /
Statement of responsibility, etc. created by Akanksha Gupta, Vinod Kumar and S. Uma
264 1# - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE
Place of production, publication, distribution, manufacture Bangalore :
Name of producer, publisher, distributor, manufacturer Springer,
Date of production, publication, distribution, manufacture, or copyright notice 2015.
336 ## - CONTENT TYPE
Source rdacontent
Content type term text
Content type code txt
337 ## - MEDIA TYPE
Source rdamedia
Media type term unmediated
Media type code n
338 ## - CARRIER TYPE
Source rdacarrier
Carrier type term volume
Carrier type code nc
440 ## - SERIES STATEMENT/ADDED ENTRY--TITLE
Title Journal of chemical sciences
Volume/sequential designation Volume 127, number 2,
520 3# - SUMMARY, ETC.
Summary, etc. A new series of layered oxides, Li3(Li1.5xFe3−(x+1.5x)Tex)O6, (0.1 ≤x≤ 1.0) possessing rocksalt superstructures crystallizing in monoclinic (S.G. C2/m) symmetry is reported here. Investigations based on single crystal and powder X-ray diffraction studies for the x= 1 member, Li3(Li1.5Fe0.5Te)O6, (a= 5.1834(1); b= 8.8858(2); c= 5.16840(8) Å; β= 110.660(1)∘) confirmed the stabilization of (Li1.5Fe0.5Te1.0 O6)3− honeycomb arrays with a very high amount of lithium ions. The structure for the x= 0.5 member (Li3.75Fe1.75Te0.5O6) has also been confirmed by the powder X-ray diffraction Rietveld refinements. Li3(Li1.5Fe0.5Te)O6 and Li3(Li0.75Fe1.75Te0.5)O6 oxides exhibited Curie–Weiss behaviour in the temperature range of 50–300 K with negative 𝜃 values. Their respective ionic conductivities were found to be 6.76×10−5 S cm−1 and 2.21 × 10−6 S cm−1 at 573 K. The UV-visible diffuse reflectance measurements for the different members of the series Li3(Li1.5xFe3−(x+1.5x)Tex)O6, 0.1 ≤ x ≤ 1.0) show the expected shifts in their absorption edges based on the increasing amount of Fe3+ ions starting from x= 1.0 member to x= 0.1 member.
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Lithium-based oxides
Form subdivision Rocksalt superstructures
General subdivision Single crystal XRD
700 1# - ADDED ENTRY--PERSONAL NAME
Personal name Kumar, Vinod
Relator term co author
700 1# - ADDED ENTRY--PERSONAL NAME
Personal name S. Uma
Relator term co author
856 ## - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier https://doi.org/10.1007/s12039-015-0784-3
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Source of classification or shelving scheme Library of Congress Classification
Koha item type Journal Article
Holdings
Withdrawn status Lost status Source of classification or shelving scheme Damaged status Not for loan Home library Current library Shelving location Date acquired Serial Enumeration / chronology Total Checkouts Full call number Date last seen Price effective from Koha item type Public note
    Library of Congress Classification     Main Library Main Library - Special Collections 02/10/2015 Vol. 127, no. (pages 225-233)   QD31 JOU 11/03/2025 11/03/2025 Journal Article For in house use only