MARC details
| 000 -LEADER |
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| fixed length control field |
02348nam a22002537a 4500 |
| 003 - CONTROL NUMBER IDENTIFIER |
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| control field |
ZW-GwMSU |
| 005 - DATE AND TIME OF LATEST TRANSACTION |
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| control field |
20250311101503.0 |
| 008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION |
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| fixed length control field |
250311b |||||||| |||| 00| 0 eng d |
| 022 ## - INTERNATIONAL STANDARD SERIAL NUMBER |
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| International Standard Serial Number |
09743626 |
| 040 ## - CATALOGING SOURCE |
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| Original cataloging agency |
MSU |
| Language of cataloging |
English |
| Transcribing agency |
MSU |
| Description conventions |
rda |
| 050 00 - LIBRARY OF CONGRESS CALL NUMBER |
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| Classification number |
QD31 JOU |
| 100 1# - MAIN ENTRY--PERSONAL NAME |
|---|
| Personal name |
Khakhlary, Prithiviraj |
| Relator term |
aouthor |
| 245 10 - TITLE STATEMENT |
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| Title |
Studies on cluster, salt and molecular complex of zinc-quinolinate / |
| Statement of responsibility, etc. |
created by Prithiviraj Khakhlary and Jubaraj B. Baruah |
| 264 1# - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE |
|---|
| Place of production, publication, distribution, manufacture |
Bangalore : |
| Name of producer, publisher, distributor, manufacturer |
Springer, |
| Date of production, publication, distribution, manufacture, or copyright notice |
2015. |
| 336 ## - CONTENT TYPE |
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| Source |
rdacontent |
| Content type term |
text |
| Content type code |
txt |
| 337 ## - MEDIA TYPE |
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| Source |
rdamedia |
| Media type term |
unmediated |
| Media type code |
n |
| 338 ## - CARRIER TYPE |
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| Source |
rdacarrier |
| Carrier type term |
volume |
| Carrier type code |
nc |
| 440 ## - SERIES STATEMENT/ADDED ENTRY--TITLE |
|---|
| Title |
Journal of chemical sciences |
| Volume/sequential designation |
Volume 127, number 2, |
| 520 3# - SUMMARY, ETC. |
|---|
| Summary, etc. |
Reactions of zinc halides with 8-hydroxyquinoline (hydroxQ) in equimolar ratio were carried out in different solvents. Respective solvates of tetranuclear clusters, namely [Zn4(oxyQ)6 X 2].(solvent)2, (when X = Cl, Solvent = dimethylformamide (1), dimethylacetamide (2) and dimethysulphoxide (3); X = Br, solvent = dimethylformamide (4), oxyQ = quinolinate anion) were obtained. Bond parameters of these isostructural clusteres 1-4 are compared from their single crystal structures. Anhydrous forms of these complexes have porous packing and are thermally stable below 250∘C. Surface area of the complexes 1 and 4 are 8.933 and 6.172 m2/g, respectively. Complexes 1 and 4 can be reversibly hydrated, which is reflected in colour changes. The reaction of zinc chloride with 8-hydroxyquinoline in equimolar ratio followed by crystallization from water gave salt (HhydroxQ)2[ZnCl4] (5) and a similar reaction followed by crystallisation from 3-methylpyridine (3mepy) resulted in the molecular complex [Zn(oxyQ)2(3mepy)]. [Zn(oxyQ)2(3mepy)2].3H2O (6). Complex 5 is formed from a hydrolytic equilibrium of water with zinc chloride yielding tetrachloro zinc anion and zinc hydroxide. Taking advantage of this reaction, a composite material of ZnO@complex 5 exhibiting dual fluorescence at 450 and 575 nm on excitation at 390 nm was prepared. Fluorescence emission properties of all the complexes in solid state are compared with fluorescence emission of the ligand. |
| 650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM |
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| Topical term or geographic name entry element |
Zinc-clusters |
| Form subdivision |
Molecular complex |
| General subdivision |
Hydrolytic equilibrium |
| 700 1# - ADDED ENTRY--PERSONAL NAME |
|---|
| Personal name |
Baruah, Jubaraj B. |
| Relator term |
co author |
| 856 ## - ELECTRONIC LOCATION AND ACCESS |
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| Uniform Resource Identifier |
https://doi.org/10.1007/s12039-015-0781-6 |
| 942 ## - ADDED ENTRY ELEMENTS (KOHA) |
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| Source of classification or shelving scheme |
Library of Congress Classification |
| Koha item type |
Journal Article |