MARC details
| 000 -LEADER |
|---|
| fixed length control field |
02151nam a22002777a 4500 |
| 003 - CONTROL NUMBER IDENTIFIER |
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| control field |
ZW-GwMSU |
| 005 - DATE AND TIME OF LATEST TRANSACTION |
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| control field |
20250311072612.0 |
| 008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION |
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| fixed length control field |
250311b |||||||| |||| 00| 0 eng d |
| 022 ## - INTERNATIONAL STANDARD SERIAL NUMBER |
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| International Standard Serial Number |
09743626 |
| 040 ## - CATALOGING SOURCE |
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| Original cataloging agency |
MSU |
| Language of cataloging |
English |
| Transcribing agency |
MSU |
| Description conventions |
rda |
| 050 00 - LIBRARY OF CONGRESS CALL NUMBER |
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| Classification number |
QD31 JOU |
| 100 1# - MAIN ENTRY--PERSONAL NAME |
|---|
| Personal name |
Shakeela, K. |
| Relator term |
author |
| 245 10 - TITLE STATEMENT |
|---|
| Title |
Electrochemical behaviour of Cu(II)/Cu(I) redox couple in 1-hexyl-3-methylimidazolium chloride ionic liquid / |
| Statement of responsibility, etc. |
created by K. Shakeela, Sri Dithya Atluri, Ch Jagadeeswara Rao and Ranga Rao Gangavarapu |
| 264 1# - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE |
|---|
| Place of production, publication, distribution, manufacture |
Bangalore : |
| Name of producer, publisher, distributor, manufacturer |
Sprinter, |
| Date of production, publication, distribution, manufacture, or copyright notice |
2015. |
| 336 ## - CONTENT TYPE |
|---|
| Source |
rdacontent |
| Content type term |
text |
| Content type code |
txt |
| 337 ## - MEDIA TYPE |
|---|
| Source |
rdamedia |
| Media type term |
unmediated |
| Media type code |
n |
| 338 ## - CARRIER TYPE |
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| Source |
rdacarrier |
| Carrier type term |
volume |
| Carrier type code |
nc |
| 440 ## - SERIES STATEMENT/ADDED ENTRY--TITLE |
|---|
| Title |
Journal of chemical sciences |
| Volume/sequential designation |
Volume 127, number 1, |
| 520 3# - SUMMARY, ETC. |
|---|
| Summary, etc. |
The electrochemical behaviour of Cu(II)/Cu(I) redox couple in 1-hexyl-3-methylimidazolium chloride (C6mimCl) ionic liquid was studied using glassy carbon electrode at 375 K by cyclic voltammetry, chronopotentiometry and electrochemical impedance spectroscopy. In this electrochemical study, we have made an attempt to avoid the problem of water contamination in hygroscopic C6mimCl ionic liquid by setting the temperature at 375 K without glove box. This high temperature cyclic voltammetric study revealed two-step one electron reductions of Cu(II) to Cu(I) followed by Cu(I) to Cu metal. The reduction of Cu(II) to Cu(I) was found to be quasi-reversible at 375 K. The diffusion coefficients of Cu(II) and Cu(I), and the charge transfer rate constant of Cu(II) in C6mimCl were estimated by Randles-Ševčik equation and Nicholson’s method, respectively, and found to be consistent with the quasi-reversible process. Further, constant potential electrodeposition of metallic copper was carried out on a stainless steel electrode at 375 K and the deposit was characterised by X-ray diffraction and electron microscopy. |
| 650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM |
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| Topical term or geographic name entry element |
Copper |
| Form subdivision |
Ionic liquid |
| General subdivision |
Electrodeposition |
| 700 1# - ADDED ENTRY--PERSONAL NAME |
|---|
| Personal name |
Atluri, Sri Dithya |
| Relator term |
co author |
| 700 1# - ADDED ENTRY--PERSONAL NAME |
|---|
| Personal name |
Rao, Ch Jagadeeswara |
| Relator term |
co author |
| 700 1# - ADDED ENTRY--PERSONAL NAME |
|---|
| Personal name |
Gangavarapu, Ranga Rao |
| Relator term |
co author |
| 856 ## - ELECTRONIC LOCATION AND ACCESS |
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| Uniform Resource Identifier |
https://doi.org/10.1007/s12039-014-0758-x |
| 942 ## - ADDED ENTRY ELEMENTS (KOHA) |
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| Source of classification or shelving scheme |
Library of Congress Classification |
| Koha item type |
Journal Article |