MARC details
000 -LEADER |
fixed length control field |
02237nam a22002657a 4500 |
003 - CONTROL NUMBER IDENTIFIER |
control field |
ZW-GwMSU |
005 - DATE AND TIME OF LATEST TRANSACTION |
control field |
20230405153313.0 |
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION |
fixed length control field |
230405b |||||||| |||| 00| 0 eng d |
040 ## - CATALOGING SOURCE |
Original cataloging agency |
MSU |
Transcribing agency |
MSU |
Description conventions |
rda |
100 ## - MAIN ENTRY--PERSONAL NAME |
Personal name |
HUANG, Jui-Yuan |
245 ## - TITLE STATEMENT |
Title |
Removal of 2,4-dichlorophenol and pentachlorophenol from aqueous media by electrochemical process |
264 ## - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE |
Place of production, publication, distribution, manufacture |
Verlag |
Name of producer, publisher, distributor, manufacturer |
Springer |
Date of production, publication, distribution, manufacture, or copyright notice |
2013 |
336 ## - CONTENT TYPE |
Source |
rdacontent |
Content type term |
text |
Content type code |
txt |
337 ## - MEDIA TYPE |
Source |
rdamedia |
Media type term |
unmediated |
Media type code |
n |
338 ## - CARRIER TYPE |
Source |
rdacarrier |
Carrier type term |
volume |
Carrier type code |
nc |
440 ## - SERIES STATEMENT/ADDED ENTRY--TITLE |
Title |
Environmental earth sciences |
Volume/sequential designation |
Volume , number , |
520 ## - SUMMARY, ETC. |
Summary, etc. |
Chlorophenols are persistent toxins in the natural environment. In this investigation, 2,4-dichlorophenol (2,4-DCP) and pentachlorophenol (PCP) in aqueous media were degraded using an electrokinetic process (EK) and an electro-Fenton process (EF) using stainless steel and graphite as the anode and cathode, respectively. Chlorophenols were degraded via direct electrolysis at the surface of the electrode in the EK process. However, in the EF process, the degradation mechanism includes direct electrolysis and oxidation by hydroxyl radicals. The optimal conditions were a current density of 0.75 mA/cm2 and an air flow of 0.7 l/min at pH 4. Under the optimal conditions, the 2,4-DCP and PCP removal rates in the EF process were 80.18 and 64.03 %, respectively. The mineralization efficiencies of 2,4-DCP and PCP were 78.23 and 75.77 %, respectively. The results of dechlorination reveal that almost all of the chlorines were released, but some were retained in the intermediates. The dechlorination efficiency revealed that the EF and EK4 processes two chlorines from 2,4-DCP. They released four or five chlorines and four chlorines from PCP, respectively. The kinetic results provide evidence of pseudo-first degradation. The rate constant (k cp) declined as pHi was increased from 4 to 10. The k cp values reveal that the pH is an important factor that affects the degradation efficiency in the electrochemical process. |
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM |
Topical term or geographic name entry element |
electrokinetic |
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM |
Topical term or geographic name entry element |
electro-fenton |
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM |
Topical term or geographic name entry element |
2,4-Dichlorophenol |
700 ## - ADDED ENTRY--PERSONAL NAME |
Personal name |
LIAO, Wing-Ping |
700 ## - ADDED ENTRY--PERSONAL NAME |
Personal name |
LAI, Siou-Mei |
856 ## - ELECTRONIC LOCATION AND ACCESS |
Uniform Resource Identifier |
https://doi.org/10.1007/s12665-012-1914-6 |
942 ## - ADDED ENTRY ELEMENTS (KOHA) |
Source of classification or shelving scheme |
Library of Congress Classification |
Koha item type |
Journal Article |