Midlands State University Library

Removal of 2,4-dichlorophenol and pentachlorophenol from aqueous media by electrochemical process (Record no. 161613)

MARC details
000 -LEADER
fixed length control field 02237nam a22002657a 4500
003 - CONTROL NUMBER IDENTIFIER
control field ZW-GwMSU
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20230405153313.0
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 230405b |||||||| |||| 00| 0 eng d
040 ## - CATALOGING SOURCE
Original cataloging agency MSU
Transcribing agency MSU
Description conventions rda
100 ## - MAIN ENTRY--PERSONAL NAME
Personal name HUANG, Jui-Yuan
245 ## - TITLE STATEMENT
Title Removal of 2,4-dichlorophenol and pentachlorophenol from aqueous media by electrochemical process
264 ## - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE
Place of production, publication, distribution, manufacture Verlag
Name of producer, publisher, distributor, manufacturer Springer
Date of production, publication, distribution, manufacture, or copyright notice 2013
336 ## - CONTENT TYPE
Source rdacontent
Content type term text
Content type code txt
337 ## - MEDIA TYPE
Source rdamedia
Media type term unmediated
Media type code n
338 ## - CARRIER TYPE
Source rdacarrier
Carrier type term volume
Carrier type code nc
440 ## - SERIES STATEMENT/ADDED ENTRY--TITLE
Title Environmental earth sciences
Volume/sequential designation Volume , number ,
520 ## - SUMMARY, ETC.
Summary, etc. Chlorophenols are persistent toxins in the natural environment. In this investigation, 2,4-dichlorophenol (2,4-DCP) and pentachlorophenol (PCP) in aqueous media were degraded using an electrokinetic process (EK) and an electro-Fenton process (EF) using stainless steel and graphite as the anode and cathode, respectively. Chlorophenols were degraded via direct electrolysis at the surface of the electrode in the EK process. However, in the EF process, the degradation mechanism includes direct electrolysis and oxidation by hydroxyl radicals. The optimal conditions were a current density of 0.75 mA/cm2 and an air flow of 0.7 l/min at pH 4. Under the optimal conditions, the 2,4-DCP and PCP removal rates in the EF process were 80.18 and 64.03 %, respectively. The mineralization efficiencies of 2,4-DCP and PCP were 78.23 and 75.77 %, respectively. The results of dechlorination reveal that almost all of the chlorines were released, but some were retained in the intermediates. The dechlorination efficiency revealed that the EF and EK4 processes two chlorines from 2,4-DCP. They released four or five chlorines and four chlorines from PCP, respectively. The kinetic results provide evidence of pseudo-first degradation. The rate constant (k cp) declined as pHi was increased from 4 to 10. The k cp values reveal that the pH is an important factor that affects the degradation efficiency in the electrochemical process.
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element electrokinetic
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element electro-fenton
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element 2,4-Dichlorophenol
700 ## - ADDED ENTRY--PERSONAL NAME
Personal name LIAO, Wing-Ping
700 ## - ADDED ENTRY--PERSONAL NAME
Personal name LAI, Siou-Mei
856 ## - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier https://doi.org/10.1007/s12665-012-1914-6
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Source of classification or shelving scheme Library of Congress Classification
Koha item type Journal Article
Holdings
Withdrawn status Lost status Source of classification or shelving scheme Damaged status Not for loan Home library Current library Shelving location Date acquired Serial Enumeration / chronology Total Checkouts Full call number Date last seen Price effective from Koha item type Public note
    Library of Congress Classification     Main Library Main Library - Special Collections 05/04/2023 Vol.68 , No.8 (Apr 2013)   GE105 ENV 05/04/2023 05/04/2023 Journal Article For In House Use Only