Midlands State University Library

Analysis of the surface of different marbles by X-ray photoelectron spectroscopy (XPS) to evaluate decay by SO2 attack (Record no. 160928)

MARC details
000 -LEADER
fixed length control field 02633nam a22002777a 4500
003 - CONTROL NUMBER IDENTIFIER
control field ZW-GwMSU
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20230223153541.0
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 230223b |||||||| |||| 00| 0 eng d
040 ## - CATALOGING SOURCE
Original cataloging agency MSU
Transcribing agency MSU
Description conventions rda
100 ## - MAIN ENTRY--PERSONAL NAME
Personal name LUQUE, A
245 ## - TITLE STATEMENT
Title Analysis of the surface of different marbles by X-ray photoelectron spectroscopy (XPS) to evaluate decay by SO2 attack
264 ## - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE
Place of production, publication, distribution, manufacture Verlag
Name of producer, publisher, distributor, manufacturer Springer
Date of production, publication, distribution, manufacture, or copyright notice 2013
336 ## - CONTENT TYPE
Source rdacontent
Content type term text
Content type code txt
337 ## - MEDIA TYPE
Source rdamedia
Media type term unmediated
Media type code n
338 ## - CARRIER TYPE
Source rdacarrier
Carrier type term volume
Carrier type code nc
440 ## - SERIES STATEMENT/ADDED ENTRY--TITLE
Title Environmental earth science
Volume/sequential designation Volume , number ,
520 ## - SUMMARY, ETC.
Summary, etc. Atmospheric pollution is one of the main agents of decay in monuments and other works of art located in industrialised urban centres. SO2 is a permanent and abundant component of air pollution and, although it does not have an immediate visual effect, after continuous exposure, it can cause irreversible damage to building materials. Marble is one of the most commonly used ornamental stones in historical monuments and its mineralogical composition makes it very susceptible to damage caused by exposure to SO2. To measure the chemical reactions caused on marble by the action of atmosphere rich in SO2, selected calcitic and dolomitic samples were altered by weathering accelerated test. For this, seven marble types (four calcitic and three dolomitic) were exposed to high concentration of sulphur dioxide for 24 h in a climate chamber under controlled temperature and humidity conditions (20 °C and > 90 % HR). Changes on marble surfaces caused by reactions of SO2 with calcite and dolomite were studied using two non-destructive techniques: chromatic change by means of colorimetry and chemical analysis using X-ray photoelectron spectroscopy (XPS). The development of new mineral phases was also observed by scanning electron microscopy. Colorimetric analysis revealed a decrease in lightness and chromatic parameters suggesting that these changes were due to the development of new mineral phases in all marbles. The XPS technique, which is generally used in the analysis of metals, is relatively new in the field of stone deterioration. It enabled us to recognise the development of sulphites and sulphates on marble surfaces with high precision, after just 24 h of exposure to high SO2 concentrations and to distinguish different decay paths for calcitic and dolomitic marbles.
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element XPS
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element calcium sulphite
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element marble decay
700 ## - ADDED ENTRY--PERSONAL NAME
Personal name MARTINEZ DE YUSO, M.V
700 ## - ADDED ENTRY--PERSONAL NAME
Personal name CULTRONE, G
700 ## - ADDED ENTRY--PERSONAL NAME
Personal name SEBASTIAN, E
856 ## - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier https://doi.org/10.1007/s12665-012-1786-9
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Source of classification or shelving scheme Library of Congress Classification
Koha item type Journal Article
Holdings
Withdrawn status Lost status Source of classification or shelving scheme Damaged status Not for loan Home library Current library Shelving location Date acquired Serial Enumeration / chronology Total Checkouts Full call number Date last seen Price effective from Koha item type Public note
    Library of Congress Classification     Main Library Main Library - Special Collections 23/02/2023 Vol.68 , No.3 (Feb 2013)   GE105 CRI 23/02/2023 23/02/2023 Journal Article For In House Use Only